Pesticides — how to read the material This is the first article in a series by research scientist Shona Kelly that will talk about pesticides in tree nurseries and sawmills. In this article Ms. Kelly, a research- er at the Division of Occupa- tional and Environmental Health at the University of B.C.’s Department of Healthcare and Epidemiology, will define the term pesticide, and explain how to read a label or material safety data sheet. In the second article she will explain measures of tox- icity, how pesticides enter our body and protective equipment. The third article will concen- trate on the pesticides used by tree nursery.workers. The fourth and final article will examine the anti-sapstain pesticides used in sawmills, ESTICIDES are legal poisons — chemical substances used to kill or control pests. I use the phrase “legal poisons” deliberately. Pesticides are in- deed poisons — just as is everything else in our environment. Even every- day substances like table salt and oxygen can be hazardous if we are exposed to high doses. As a famous man in the 14th century said (and I paraphrase) — all things are toxic, it is only the dose that matters. In Canada, pesticides are legally controlled substances. This means their availability and use in Canada are controlled by regulations. Agri- culture Canada, in consultation with Health and Welfare Canada, Environ- ment Canada, and Fisheries and Oceans Canada, decides which prod- ucts can be sold in Canada. These decisions are based on reviews of toxi- cology tests, laboratory and field stud- ies of the persistence of the product and also the use for which the pesti- cide will be applied. This last one sounds obvious, but in Canada, unlike the U.S., we do not bring in new, relatively untested products when old, well understood products are still effec- tive. Sometimes problems associated with a pesticide may take years to discover and Agriculture Canada tends to be more cautious than their US. counterparts. DEFINITION OF A PESTICIDE In Canada the term pesticide includes all the subgroups listed in Table 1. The popular press tends to refer to ‘pesticides and herbicides’ — perhaps because herbicides are con- sidered non-toxic. I just want to remind you that paraquat is a herbi- cide! Many people feel that biocide (literally meaning ‘killer of life’) is a better term than pesticide. The word biocide more accurately describes that fact that other forms of life besides the target pests can be affected when After being manufactured in a rela- tively pure form, the pesticide is then formulated. The formulation is the form in which the pesticide is sold for use or, to put it another way, the pesticide is processed into a useable form. Pesticides are formulated to improve their properties of storage, handling, effectiveness, or safety. This does not include any dilution done by a pesticide applicator at the applica- tion site. Table 2 is a list, by no means complete, of the different types of formulations. The part of the prod- uct that kills the pest is called the “active ingredient,” the other parts of the product are called “inert ingredi- ents.” The words active and inert refer only to the way the pesticide affects the pest and not on how hazardous they may be to other organisms like humans. Don’t be intimidated by the terminology used in this table. I’ve included the information so that the .« pesticide label becomes less intimi- dating. For example, EC in a pesti- cide name means the product is an emulsifiable concentrate. WP means it is a wettable powder. READING A LABEL Now, lets look at a label. The first thing you must understand about a label is that it is a legal agreement between the purchaser and the manu- facturer. By purchasing the product you are agreeing to use the product as indicated on the label. It is illegal to use a pesticide product for any pur- pose not described on the label. Prod- ucts introduced to the market recently tend to have better labels than prod- ucts that have been available for a long time. Agriculture Canada is work- ing with manufacturers to improve all labels but this takes time. Now, lets look at the information available on the label. 1. Trade Name — this is the “brand name.” It does not often contain the name of the active ingredient, but the name may contain the let- formulation. It is important that you know the complete name because closely related products may have similar names but differ- ent ingredients. Emulsifiable con- centrates may contain toxic petro- leum distillates while wettable powders do not. The proper name of a pesticide product is critical when poisoning has occurred and doctors are trying to treat the patient. . Guarantee — this gives the amount and name of the active ingredient. If the “inert” ingredients are toxic they will often be listed here as well. . Pesticide Use — a statement which, in a general way, describes what the product is to be used for. For example, Vision is a herbicide for use in forestry. . Marketing Code — this describes who can use the product. — domestic is for untrained users in the home and garden. — commercial is for either Agricul- ture or Industrial use and the workers are expected to have had some training. — restricted is for application by licensed applicators only and usu- ally requires a special permit issued by federal or provincial pes- ticide regulators. . Warning Symbols — are not exactly the same as those used by WHMIS but the underlying prin- cipals are similar. A “stop sign” is used on the most toxic pesticides, a diamond-shaped sign warns of moderate toxicity, and a “yield sign” cautions of slight toxicity. The symbols enclosed in these signs may be a skull & crossbones for poisonous products, a fire sym- bol for flammable products, an “exploding grenade” for potentially explosive products, or a corroded hand for corrhosive products. . Precautions — state what protec- tive equipment should be worn while using the product. Older labels tend to be vague here but newer labels will even specify the type of respirator cartridge or the material that gloves should be a, cw - © Research Scientist Shona Kelly made from. For older products it is best to contact the manufacturer directly and find out what they recommend. . Directions for use — this is general information on how the product is to be applied to control the pest. Most products have a separai detailed application guide avail- able. New ones should be obtained each year as the information is constantly being updated and improved. Do not confuse the appli- cation guide with the Material Safety Data Sheet (MSDS). . First Aid and Toxicological Infor- mation — is a brief summary of any poisoning symptoms. Much more detailed information is avail- able on the MSDS. The manufac- turers should be contacted every year to check for new versions of the MSDS. The MSDS will also have the most recent Emergency phone number. There have been many changes in the pesticide mar- ket in Canada and phone numbers found on products purchased more than 6 months ago may not be accurate. |. Registration Number — this is the Pest Control Products Act (PCP) Number that is given to the prod- uct by Agriculture Canada. Each TABLE 2 PESTICIDE FORMULATIONS Products such as bug bombs, Raid”. Contain an insect attractant and may also contain a pool of insecticide. Usually pesticide-treated foods for control of animals and birds. Finely powdered dry other finely powde: aerosols attractant traps baits dusts emulsifiable concentrate e sticides mixed with dry substances. a pesticide is used. ters EC or WP, which describe its acaricide/miticide algicide animal repellant animal toxicant bactericide bird repellant bird toxicant/avicide disinfectant fish toxicant/piscicide fungicide herbicide insect repellant insecticide materials preservative molluscicide nematicide plant growth regulator pruning paint rodenticide slimicide wood preservative PESTICIDE GROUPS — BY TYPE OF PEST KILLED TABLE 1 kills mites and ticks kills algae repels animals but does not kill them kills large animals like coyotes kills or slows the growth of bacteria repels bird but does not kill them kills birds same as a bactericide kills fish kills fungi kills plants repels insects but does not kill them kills insects e.g. mildew preventers in fabric kills snails, slugs, clams, etc. kills nematodes increases or decreases plant growth a physical barrier to protect tree wounds kills rodents kills slime, e.g. in swimming pools flowable suspension fumigants granulars impregnated material oil solutions slow release soluble pellets ultra-low volume concentrates wettable power Oily solutions to which an emulsifier is added to make them mixable with water. A “pudding-like” product that flows easily into the spray tank where it is mixed with water and kept in suspension by constant mixing. Pesticides that are gases at room temperature and therefore can enter every crack and crevice to kill pests. Larger particles than dusts. e.g.s. wood-preservative soaked clothes, No-pest Strips’, flea collars. Pesticide is dissolved in oil and is applied as an oil spray. Water is NEVER added but kerosene or diesel fuel may be used to dilute it. e.g. micro-encapsulated pesticides, impregnat resin strips. Large blocks of pesticide impregnated solids that are designed to dissolve in watér. Often available to homeowners for use with a hose attachment. Usually consists of the pesticide dissolved in a minimum of solvent ada are applied without. further dilution by special equipment that emits an extremely fine spray. A dust combined with a wetting agent to make the mixing of the powder with water easier. They don’t actually dissolve but are suspended in the water and must be constantly stirred. a 10/LUMBERWORKER/APRIL, 1992